Engine oils contain several additives dissolved or dispersed in a hydr
ocarbon oil base. Each of these additives are meant to perform one or
more functions, which may or may not relate directly to friction and w
ear. The performance of additive mixtures, however, cannot usually be
predicted in a simple fashion, such as, for example, by a rule-of-mixt
ures approach. In addition, additives which are meant to perform funct
ions unrelated to friction and wear may impact the efficacy of frictio
n and wear additives. Many of these effects can be explained by the st
udy of additive interactions by various spectroscopic, colligative and
other physical chemical methods. This paper presents a review of publ
ished information on that topic, with a view to stimulate further work
as well as to provide insight on issues facing engine oil formulators
.