The solid-phase microextraction (SPME) is a new method for the extract
ion of organic compounds from environmental samples which eliminates t
he use of solvents. Stationary phases coating fused silica fibre are u
sed to extract the analytes from the sample. After extraction the sorb
ed substances are introduced into the GC system, where they are therma
lly desorbed and analyzed. The SPME methods are classified according t
o the physical-chemical principle as direct methods and headspace meth
ods. The review deals mainly with the utilization of SPME for the prec
oncentration of organic pollutants from environmental matrices giving
100 references.