Corrosion of reinforcement bars due to chloride ingress is a well know
n problem in reinforced concrete. Several methods have been adopted to
protect reinforced concrete, and one of them is to provide added prot
ection to the concrete surface in the form of surface treatments such
as silanes and siloxanes. They react with the cement matrix and form a
hydrophobic layer on the walls of the pores within the concrete. This
protects the concrete from the ingress of water and water-born salts.
Moisture is required for reaction of silanes and siloxanes with the h
ydrated cement matrix. However, too much water in the pores of concret
e will prevent the treatments from penetrating deeper into the pores.
A study has been carried out to investigate the variation, due to the
presence of moisture, on the effectiveness of the protection. It has b
een found that irrespective of the moisture content at the time of app
lication of treatment, silanes and siloxanes provided good protection
against chloride ingress and corrosion of reinforcement bars. However,
the depth of penetration and therefore the durability of the treatmen
t is adversely affected when the concrete is near saturation.