M. Andrieux et al., OPTICAL-EMISSION SPECTROSCOPY OF RF AND MICROWAVE PLASMAS USED FOR CHEMICAL-VAPOR-DEPOSITION IN THE SI-C-H-AR SYSTEM, Annales de chimie, 23(5-6), 1998, pp. 743-752
This work highlights optical emission spectroscopy (OES) results used
for a better understanding of processes occuring in radiofrequency and
microwave plasma enhanced chemical vapor deposition in the Si-C-H-Ar
gas system, Optical lines such as Si+ and H-alpha (lambda = 634.71; 65
6.29 nm), C-2 (lambda = 516.52 nm), CH and SiH (lambda = 431.42; 412.8
0 nm) can be considered as tracers of chemical species in the plasmas.
Process parameters (growth rate, composition, residual stresses in th
e films and gas temperature) have their optical signatures (respective
ly : Si+, H-alpha lines and rotational G(1)Sigma(+)g --> B(1)Sigma(+)u
structure of H-2).