The authors examined the effect of electrochemically active and barrie
r-effect pigments in various primers. The efficiency of an anti-corros
ion pigment proved to be significantly dependent on the properties of
the coating concerned, and particularly on its barrier properties. If
the permeability of a primer is low, the protective effect of the barr
ier pigment will be predominant. On the other hand, the effect of an i
nhibitive pigment will be more apparent in coatings with a certain deg
ree of permeability since the solubility of the pigment and the mass t
ransfer conditions within the coating will be important in this case.