The characteristic features of electronic spectra in Ge/Si (100) heter
ostructures obtained by molecular-beam epitaxy are investigated by cap
acitance spectroscopy. It is observed that the self-organization of a
Ge film into an island film when the effective germanium thickness exc
eeds six monolayers is accompanied by the appearance of hole bound sta
tes, which can be attributed to size quantization and the Coulomb inte
raction of carriers in the array of Ge quantum dots. (C) 1998 American
Institute of Physics.