In 1996 and 1997 the Galileo Ultraviolet Spectrometer (WS) obtained th
e first measurements of Jupiter's nightside midultraviolet (MUV) polar
auroral spectrum from 1620 to 3231 Angstrom at 13 Angstrom resolution
. The reduced polar spectra, after removal of off-axis scattered radia
tion from the sunlit dayside of Jupiter, contain a spectrum that match
es laboratory spectra of the H-2 continuum in the a-b dissociative emi
ssion transition. This is the first direct identification of the H-2 a
-b transition in astronomy. The a-b emission is excited by electron im
pact exchange reactions with H-2 that peak in cross section near 15 eV
. The emission threshold is at 1216 Angstrom, and the continuum peaks
in intensity in the 2000-2500 Angstrom range. Jupiter's observed wavel
ength-integrated MUV H-2 a-b emissions (1620-3231 Angstrom) have a pho
ton flux similar to 8 times smaller than simultaneously observed wavel
ength-integrated far-ultraviolet (FUV) H-2 band emissions (1230-1650 A
ngstrom). Because the FUV H-2 emissions have an emission cross section
that peaks at higher energies near 50 eV, this FUV/MUV brightness rat
io is diagnostic of the secondary electron energy distribution and is
consistent with a ''warm'' distribution of electrons.