FIRST EXPERIMENTAL-EVIDENCE FOR THE FORMATION OF A SILICATE ANION BY INTRAMOLECULAR ADDITION OF A PERSULFOXIDE TO A TRIMETHYLSILOXY GROUP

Authors
CLENNAN EL DILLON DL
Citation
El. Clennan et Dl. Dillon, FIRST EXPERIMENTAL-EVIDENCE FOR THE FORMATION OF A SILICATE ANION BY INTRAMOLECULAR ADDITION OF A PERSULFOXIDE TO A TRIMETHYLSILOXY GROUP, Tetrahedron letters, 39(38), 1998, pp. 6827-6830
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
38
Year of publication
1998
Pages
6827 - 6830
Database
ISI
SICI code
0040-4039(1998)39:38<6827:FEFTFO>2.0.ZU;2-8
Abstract
The photooxidation of an alpha-trimethylsiloxysulfide has been studied . The reaction generates a persulfoxide which can be trapped by diphen ylsulfoxide, decompose to generate triplet oxygen and substrate, or re arrange to a silicate product via a silicate intermediate. (C) 1998 El sevier Science Ltd. All rights reserved.