LIGAND-EXCHANGE REACTION OF SULFOXIDES IN ORGANIC-SYNTHESIS - SULFOXIDE VERSION OF THE JULIA-LYTHGOE OLEFINATION

Authors
SATOH T YAMADA N ASANO T
Citation
T. Satoh et al., LIGAND-EXCHANGE REACTION OF SULFOXIDES IN ORGANIC-SYNTHESIS - SULFOXIDE VERSION OF THE JULIA-LYTHGOE OLEFINATION, Tetrahedron letters, 39(38), 1998, pp. 6935-6938
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
38
Year of publication
1998
Pages
6935 - 6938
Database
ISI
SICI code
0040-4039(1998)39:38<6935:LROSIO>2.0.ZU;2-Q
Abstract
Reaction of beta-mesyloxy sulfoxides, derived from alkyl (or arylmethy l) pheny] sulfoxides and aldehydes in two steps, with alkylmetal (n-Bu Li, t-BuLi, or EtMgBr) at -78 degrees C gave olefins in good to excell ent yields. This reaction offers a sulfoxide version of the Julia-Lyth goe olefination. (C) 1998 Elsevier Science Ltd. All rights reserved.