(DIETHYLENETRIAMINE)BIS(ISOTHIOCYANATO)ZINC(II)

Authors
LU TH LO JM CHEN BH YEH MY TUNG SF HUANG WT YAO HH
Citation
Th. Lu et al., (DIETHYLENETRIAMINE)BIS(ISOTHIOCYANATO)ZINC(II), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1067-1068
Citations number
16
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
8
Pages
1067 - 1068
Database
ISI
SICI code
0108-2701(1998)54:<1067:(>2.0.ZU;2-D
Abstract
In the X-ray crystal structure of the title complex, nediamine-kappa(3 )N]bis(isothiocyanato-N)zinc(II), [Zn(NCS)(2)(C4H13N3)], the Zn-II ion and the two isothiocyanate groups lie on a mirror plane and the dieth ylenetriamine ligand is disordered. The Zn-II ion is coordinated to th e three N atoms of the diethylenetriamine ligand and to the N atoms of two isothiocyanate ions. The primary coordination sphere about the Zn -II ion can be regarded as a symmetric trigonal bipyramid. The ordered Zn-N distances range from 1.984(7) to 2.252 (8) Angstrom.