-TRIOXA-1-PHOSPHABICYCLO[2.2.2]OCTANE-P)RHODIUM(I)

Authors
ERASMUS JJC LAMPRECHT GJ KOHZUMA T NAKANO Y
Citation
Jjc. Erasmus et al., -TRIOXA-1-PHOSPHABICYCLO[2.2.2]OCTANE-P)RHODIUM(I), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1085-1087
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
8
Pages
1085 - 1087
Database
ISI
SICI code
0108-2701(1998)54:<1085:->2.0.ZU;2-H
Abstract
The bicyclic phosphite -methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]oct ane reacts in a 1:1 molar ratio with yl(1,3-diphenyl-1,3-propanedionat o-O,O')rhodium(I) to yield the title compound, [Rh(C15H11O2)-(C5H9O3P) (CO)], with square-planar geometry about the Rh atom. The Rh-P bond di stance is 2.1690 (11) Angstrom.