EXOPOLYHEDRAL CYCLIZED PLATINAUNDECABORANES - [(PPH3)(PHCOS)PTB10H11].0.5CH(2)CL(2)

Authors
HU CH DOU JM SUN J YAO HJ WEI JD JIN RS ZHENG PJ
Citation
Ch. Hu et al., EXOPOLYHEDRAL CYCLIZED PLATINAUNDECABORANES - [(PPH3)(PHCOS)PTB10H11].0.5CH(2)CL(2), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1089-1091
Citations number
27
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
8
Pages
1089 - 1091
Database
ISI
SICI code
0108-2701(1998)54:<1089:ECP-[>2.0.ZU;2-M
Abstract
The asymmetric unit of the title compound 7,11- or oato-S:O)-7-(triphe nylphosphine-P)-8,9:10,11-di-mu H-7-platina-nido-undecaborane-dichloro -methane (1/0.5), C25H31B10OPPtS.0.5CH(2)Cl(2), contains two metallabo rane molecules, which are approximate geometric isomers, and one molec ule of dichloro-methane solvent. Each isomer has an exopolyhedral thio benzoate ligand bridging one Pt and one B atom to give a five-membered Pt-S-C-O-B ring.