NTHROLINE-N,N')(MU-3-THIOSULFATO-S-S-O)CADMIUM(II) HYDRATE

Authors
BAGGIO S BAGGIO R GARLAND MT
Citation
S. Baggio et al., NTHROLINE-N,N')(MU-3-THIOSULFATO-S-S-O)CADMIUM(II) HYDRATE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1099-1102
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
8
Pages
1099 - 1102
Database
ISI
SICI code
0108-2701(1998)54:<1099:NH>2.0.ZU;2-E
Abstract
The structure of [Cd(S2O3)(C12H8N2)(H2O)]. H2O is reported. It consist s of polymeric chains evolving along the 2(1) symmetry axis, interconn ected by hydrogen bonds. The Cd2+ environment is a distorted octahedro n Which presents a rather long Cd-O distance [2.549 (4) Angstrom]. The thiosulfate ion binds to three different cationic sites, through one singly coordinated O atom and one S atom acting in a bridging mode.