The structure of [Pt-2(C6H5S)(2)(C6H15P)(4)](PF6)(2) has been determin
ed by single-crystal X-ray diffraction at room temperature. The cation
has C-i symmetry with a square-planar-coordinated Pt atom. The centra
l Pt2S2 ring is a rhombus with angles S-Pt-S' 81.34(5) and Pt-S-Pt' 98
.66 (5)degrees.