C. Wieserjeunesse et al., SYNTHESIS AND PROPERTIES OF PHOSPHORUS-CONTAINING CALIX[4]ARENES, COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 1(8), 1998, pp. 479-502
This is an exhaustive review of phosphorus-functionalized calix[4]aren
es. Effective methodologies are described that allow preparation of de
rivatives with phosphate, phosphonate, phosphine oxide and P(III)-cont
aining groups. It is shown that phosphoryl-containing calix[4] arenes
display interesting ionophoric properties, in particular with respect
to the extraction and separation of lanthanides and actinides. (C) Aca
demie des sciences/Elsevier, Paris.