A. Fontana et al., FIRST CHEMICAL STUDY OF PATAGONIAN NUDIBRANCHS - A NEW SECO-11,12-SPONGIANE, TYRINNAL, FROM THE DEFENSIVE ORGANS OF TYRINNA-NOBILIS, Journal of natural products, 61(8), 1998, pp. 1027-1029
The Patagonian nudibranch Tyrinna nobilis contains a number of terpeno
ids, the novel seco-11,12-spongiane tyrinnal (1) and the known sesquit
erpenoids dendrolasin (2), pallescensin A (3), and dehydropallescensin
-2 (4). The metabolites probably derive from dietary sponges, thus sug
gesting a parallelism between the ecological relationships of T. nobil
is and those of mollusks of genus Cadlina. The structure of 1 was dete
rmined by spectroscopic methods.