CONSECUTIVE CATALYTIC HYDROFORMYLATION-ACETALIZATION OF GLUCAL DERIVATIVES WITH RHODIUM-PHOSPHITE AND PYRIDINIUM TOLUENE-P-SULFONATE AS CATALYSTS - THE INFLUENCE OF PROTECTING GROUPS

Authors
FERNANDEZ E POLO A RUIZ A CLAVER C CASTILLON S
Citation
E. Fernandez et al., CONSECUTIVE CATALYTIC HYDROFORMYLATION-ACETALIZATION OF GLUCAL DERIVATIVES WITH RHODIUM-PHOSPHITE AND PYRIDINIUM TOLUENE-P-SULFONATE AS CATALYSTS - THE INFLUENCE OF PROTECTING GROUPS, Chemical communications, (17), 1998, pp. 1803-1804
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
17
Year of publication
1998
Pages
1803 - 1804
Database
ISI
SICI code
1359-7345(1998):17<1803:CCHOGD>2.0.ZU;2-O
Abstract
Consecutive catalytic hydroformylation-acetalization of unsaturated ca rbohydrates (glucals) to give the dimethyl acetal of 2-C-formyl-D-aldi tol derivatives using the catalytic system [Rh(mu-OMe)(cod)](2)/P(O-o- (BuC6H4)-C-t)(3)/PPTS is strongly dependent on the protecting groups o n the carbohydrate.