R. Anwander et al., ENHANCED CATALYTIC ACTIVITY OF MCM-41-GRAFTED ALUMINUM ISOPROPOXIDE IN MPV REDUCTIONS, Chemical communications, (17), 1998, pp. 1811-1812
Aluminium alkoxide moieties are grafted onto purely siliceous mesoporo
us MCM-41 via siloxide linkages, producing materials which reveal enha
nced catalytic activity in the MPV reduction of cyclic ketones; nitrog
en physisorption and Al-27 MAS NMR spectroscopy are applied to charact
erise the catalytically active hybrid systems.