CARBOXYLATION OF METHANE WITH CO OR CO2 IN AQUEOUS-SOLUTION CATALYZEDBY VANADIUM COMPLEXES

Authors
NIZOVA GV SUSSFINK G STANISLAS S SHULPIN GB
Citation
Gv. Nizova et al., CARBOXYLATION OF METHANE WITH CO OR CO2 IN AQUEOUS-SOLUTION CATALYZEDBY VANADIUM COMPLEXES, Chemical communications, (17), 1998, pp. 1885-1886
Citations number
39
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
17
Year of publication
1998
Pages
1885 - 1886
Database
ISI
SICI code
1359-7345(1998):17<1885:COMWCO>2.0.ZU;2-F
Abstract
Reaction of methane with CO or CO2 in aqueous solution in the presence of O-2 (catalysed by NaVO3) or H2O2 (catalysed by NaVO3-pyrazine-2-ca rboxylic acid) at 25-100 degrees C affords acetic acid and in some cas es also methanol, methyl hydroperoxide and formaldehyde.