SYNTHESIS AND MOLECULAR-STRUCTURE OF THE FIRST TETRANUCLEAR COPPER(I)SILYLPHOSPHIDO CLUSTER [CU(CYPSIME2PHCY)](4)

Authors
FAULHABER M DRIESS M MERZ K
Citation
M. Faulhaber et al., SYNTHESIS AND MOLECULAR-STRUCTURE OF THE FIRST TETRANUCLEAR COPPER(I)SILYLPHOSPHIDO CLUSTER [CU(CYPSIME2PHCY)](4), Chemical communications, (17), 1998, pp. 1887-1888
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
17
Year of publication
1998
Pages
1887 - 1888
Database
ISI
SICI code
1359-7345(1998):17<1887:SAMOTF>2.0.ZU;2-#
Abstract
The reaction of ,N-diethylamino(cyclohexylphosphino)dimethylsilane 1 w ith the benzene solvate of copper(I) trifluoromethylsulfonate furnishe s the title complex 2, which has been structurally characterized by X- ray diffraction; the same product results on conversion of bis(cyclohe xylphosphino)dimethylsilane 3 with copper(I) trifluoromethylsulfonate in the presence of lithium diisopropylamide as an auxilliary base.