ORTHODEUTERIUM INDUCED POLARIZATION

Authors
NATTERER J GREVE T BARGON J
Citation
J. Natterer et al., ORTHODEUTERIUM INDUCED POLARIZATION, Chemical physics letters, 293(5-6), 1998, pp. 455-460
Citations number
17
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
293
Issue
5-6
Year of publication
1998
Pages
455 - 460
Database
ISI
SICI code
0009-2614(1998)293:5-6<455:OIP>2.0.ZU;2-W
Abstract
We present a theory and experimental results for the use of orthodeute rium to obtain dramatically enhanced NMR signals of the products of de uteration reactions. Orthodeuterium was enriched in solid nitrogen at 65 K, the deuterations however were carried out at ambient temperature and pressure. The phenomenon presented should be useful for NMR inves tigations of chiral syntheses. (C) 1998 Elsevier Science B.V. All righ ts reserved.