VIBRATIONAL-MODES AND STRUCTURES OF LANTHANIDE HALIDE ALKALI HALIDE BINARY MELTS - LNBR(3)-KBR (LN=LA, ND, GD) AND NDCL3-ACL (A=LI, NA, K, CS)

Raman spectra of the following rare earth halide-alkali halide binary molten salt systems have been measured: LnBr(3)-KBr (Ln = La, Nd, Gd) and NdCl3-ACl (A = Li, Na, K, Cs). The complete composition range has been studied at temperatures up to 850 degrees C. The spectral changes occurring upon melting the elpasolite compounds Cs(2)NaLnBr(6) (Ln = La, Nd, Gd) and Cs2NaNdCl6 and the pure crystalline solids LnBr(3) (Ln = La, Nd, Gd) and NdCl3 were also measured. The data indicate that th e behavior of these melt mixtures is similar to those of the YX3-KX (X = F, Cl, Br) binaries studied before. In molten mixtures rich in alka li halide with lanthanide halide mole fractions less than 0.25, the pr edominant species;are the LnX(6)(3-) octahedra giving rise to two main bands P-1 (polarized) and D-1 (depolarized) which are assigned to the nu(1)(A(1g)) and nu(5)(F-2g) octahedral modes. In molten mixtures ric h in LnX(3) the spectra are characterized by the P-1 and D-1 bands plu s two new bands D-2 (depolarized) and P-2 (polarized). The P-2 band sh ifts continuously to higher frequencies with increasing LnX(3) content . These four bands are attributed to the D-3 distortions of the LnX(6) (3-) octahedra bound by edges in the melt. The room temperature Raman spectra of the LnX(3) solid compounds were characterized by bands due to the vibrational modes of the different crystalline structures: hexa gonal for LaBr3 and NdCl3, orthorhombic for NdBr3 and rhombohedral for GdBr3 having the Ln(3+) coordination number (CN) or 9, 8 and 6, respe ctively. With increasing temperature the spectra of the GdBr3 solid ar e dominated by six Raman bands which are assigned to the vibrational m odes of a triple layer of ions consisting of distorted octahedra GdBr6 3- (CN = 6) which share edges with neighboring octahedra. Upon melting ; the molar volume of GdBr3 does not change much and the spectra are c haracterized by the above-mentioned P-1, P-2, D-1 and D-2 bands and ca n be correlated to the triple layer modes of the solid. The high tempe rature spectra of the hexagonal LaBr3, NdCl3 and the orthorhombic NdBr 3 show that the structure and CN remain the same up to melting. Howeve r, upon melting, the compact orthorhombic (CN = 8) and hexagonal (CN = 9) forms increase drastically their molar volume and give spectra sim ilar to those of molten GdBr3, YBr3 and YCl3 where the Ln(3+) is in a six-fold coordination (CN = 6). It appears that the structures of all the LnX(3) melts are similar and independent of the structure of the s olids. The frequency changes upon melting the LnX(3) solids, the prese nce and assignment of the P-1, P-2, D-1 and D-2 bands in the spectra, the continuous shift of the P-2 band with composition in the LnX(3)-AX binaries and the correlation of the high temperature modes of the rho mbohedral LnX(3) solid (CN = 6) to the Liquid suggest that the loose n etwork structure proposed for the LnX(3) melts is more likely to arise from 'triple layer' like structures composed of distorted octahedra. The rigidity of the network is related to the splitting of the P-1 and P-2 band and increases with increasing distortion of the octahedra in the sequence La-Y; F-Br. Fast interchange of ions leads to short life times for the octahedra and weak intralayer interactions.