THE 7-COMPONENT ASSEMBLY OF THE BOWL-SHAPED CAGES K-RH-7(7)(CN)(12)(2-ASTERISK-7RH3IR4(CN)(12)(2+)() AND CP)

Authors
CONTAKES SM KLAUSMEYER KK MILBERG RM WILSON SR RAUCHFUSS TB
Citation
Sm. Contakes et al., THE 7-COMPONENT ASSEMBLY OF THE BOWL-SHAPED CAGES K-RH-7(7)(CN)(12)(2-ASTERISK-7RH3IR4(CN)(12)(2+)() AND CP), Organometallics, 17(17), 1998, pp. 3633-3635
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
17
Year of publication
1998
Pages
3633 - 3635
Database
ISI
SICI code
0276-7333(1998)17:17<3633:T7AOTB>2.0.ZU;2-F
Abstract
A novel bowl-shaped cyanometalate cage [Cp-7Rh-7(CN)(12)](2+) (3) for ms via the reaction between MeCN solutions of Et4N[CpRh(CN)(3)] and [ CpRh(NCMe)(3)](PF6)(2); this seven-component condensation proceeds in 89% yield. H-1 and C-13 NMR spectroscopic measurements as well as a s ingle-crystal X-ray diffraction studies show that 3 features a C-3 ups ilon Rh-7(CN)(9) cage, which can be described as a fragment of a Rh-8( CN)(12) box.