C-H VERSUS C-N BOND-CLEAVAGE PROMOTED BY NIOBIUM(II) AMIDE

Authors
TAYEBANI M GAMBAROTTA S YAP G
Citation
M. Tayebani et al., C-H VERSUS C-N BOND-CLEAVAGE PROMOTED BY NIOBIUM(II) AMIDE, Organometallics, 17(17), 1998, pp. 3639-3641
Citations number
59
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
17
Year of publication
1998
Pages
3639 - 3641
Database
ISI
SICI code
0276-7333(1998)17:17<3639:CVCBPB>2.0.ZU;2-W
Abstract
Despite their close structural similarity, the potassium and lithium s alts of dipyridylamine and diphenylamine [(C5H5N)(2)N-, Ph2N-] react w ith (TMEDA)(2)Nb2Cl5Li(TMEDA) in THF to afford two different compounds arising from the cooperative oxidative addition of the two metal cent ers on either the C-H or C-N bond of the amide ligand.