HIGHLY ELECTRON-DEFICIENT NEUTRAL AND CATIONIC ZIRCONIUM COMPLEXES WITH BIS(SIGMA-ARYL)AMINE DIANIONIC TRIDENTATE LIGANDS

Authors
BOUWKAMP M VANLEUSEN D MEETSMA A HESSEN B
Citation
M. Bouwkamp et al., HIGHLY ELECTRON-DEFICIENT NEUTRAL AND CATIONIC ZIRCONIUM COMPLEXES WITH BIS(SIGMA-ARYL)AMINE DIANIONIC TRIDENTATE LIGANDS, Organometallics, 17(17), 1998, pp. 3645-3647
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
17
Year of publication
1998
Pages
3645 - 3647
Database
ISI
SICI code
0276-7333(1998)17:17<3645:HENACZ>2.0.ZU;2-C
Abstract
A highly electron-deficient zirconium dibenzyl complex with a dianioni c tridentate bis(sigma-aryl)amine ligand, [(C10H6CH2)(2)NMe]Zr(CH2Ph)( 2), was prepared and structurally characterized. The cationic benzyl d erivative with the [B(C6F5)(4)](-) counterion, catalytically polymeriz es olefins, whereas with the eta(6)-[PhCH2B(C6F5)(3)](-) counterion th e system is inactive.