SYNTHESIS OF 2-ACYL-1,4-DIKETONES VIA THE DIACYLATION OF ALPHA,BETA-UNSATURATED KETONES

Authors
LI NS YU S KABALKA GW
Citation
Ns. Li et al., SYNTHESIS OF 2-ACYL-1,4-DIKETONES VIA THE DIACYLATION OF ALPHA,BETA-UNSATURATED KETONES, Organometallics, 17(17), 1998, pp. 3815-3818
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
17
Year of publication
1998
Pages
3815 - 3818
Database
ISI
SICI code
0276-7333(1998)17:17<3815:SO2VTD>2.0.ZU;2-M
Abstract
The first example of a diacylation of the carbon-carbon double bond in alpha,beta-unsaturated ketones is described. The reaction of acylcyan ocuprate reagents with alpha,beta-unsaturated ketones, followed by C-a cylation, produces 2-acyl-1,4-diketones in good yields (50-89%).