SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL POLYHETEROCYCLOPENTADIENYL THALLIUM(I) COMPLEX

Authors
FRANCIS MD JONES C DEACON GB DELBRIDGE EE JUNK PC
Citation
Md. Francis et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL POLYHETEROCYCLOPENTADIENYL THALLIUM(I) COMPLEX, Organometallics, 17(17), 1998, pp. 3826-3828
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
17
Year of publication
1998
Pages
3826 - 3828
Database
ISI
SICI code
0276-7333(1998)17:17<3826:SASCOA>2.0.ZU;2-V
Abstract
The reaction of [Li(TMEDA)(2)][1,4,2-P2SbC2-BU2t] (I) with TlCl afford s the compound l(mu-eta(5:):eta(5)-1,4,2-P2SbC2Bu2t)}(infinity)]) (2). Its X-ray crystal structure reveals a double-stranded zigzag polymeri c chain structure with intermolecular thallium-phosphorus interactions .