I. Borges et al., PHOTON AND ELECTRON-IMPACT DISSOCIATION CROSS-SECTIONS OF HCL, Journal of physics. B, Atomic molecular and optical physics, 31(16), 1998, pp. 3703-3711
We compute high-energy electron-impact (100-1000 eV) dissociation and
photodissociation cross sections of HCl producing H and CI neutral ato
ms through the X(1)Sigma(+)(upsilon = 0) --> A(1)Pi transition. The el
ectron-impact dissociation cross sections are obtained in the first Bo
rn approximation, and are reported for the first time. Hartree-Fock fo
llowed by configuration interaction wavefunctions are used and vibrati
onal degrees are considered. The dissociation cross sections as a func
tion of the continuum energy are presented. Photodissociation cross se
ctions are obtained and compared with previous theoretical and experim
ental results.