A NEW AND FACILE SYNTHETIC ROUTE TO 1-ALKYL-2-OXOPROPYLPHOSPHONATES -1-ALKYLATION WITH SUBSEQUENT OZONOLYSIS OF 2-METHYL ALLYLIC PHOSPHONATES

Authors
GIL JM PARK KY HAH JH OH DY
Citation
Jm. Gil et al., A NEW AND FACILE SYNTHETIC ROUTE TO 1-ALKYL-2-OXOPROPYLPHOSPHONATES -1-ALKYLATION WITH SUBSEQUENT OZONOLYSIS OF 2-METHYL ALLYLIC PHOSPHONATES, Synthetic communications, 28(19), 1998, pp. 3601-3607
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
19
Year of publication
1998
Pages
3601 - 3607
Database
ISI
SICI code
0039-7911(1998)28:19<3601:ANAFSR>2.0.ZU;2-7
Abstract
Alkylation of the 2-methyl allylic phosphonates is performed by treatm ent with n-BuLi, followed by addition of alkyl halides. The 1-alkyl-2- oxopropylphosphonates are obtained by the ozonolysis of the correspond ing allylic phosphonates.