AMINOSILYLGERMYLENES - (E)-DIGERMENE VERSUS GERMYLENE CRYSTALLIZATION

Authors
SCHAFER A SAAK W WEIDENBRUCH M
Citation
A. Schafer et al., AMINOSILYLGERMYLENES - (E)-DIGERMENE VERSUS GERMYLENE CRYSTALLIZATION, Zeitschrift fur anorganische und allgemeine Chemie, 624(9), 1998, pp. 1405-1408
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
9
Year of publication
1998
Pages
1405 - 1408
Database
ISI
SICI code
0044-2313(1998)624:9<1405:A-(VGC>2.0.ZU;2-6
Abstract
The diaminosilylene tBuNCH(2)CH(2)NtBuSi: reacted with the diaminogerm ylenes RNCH2CH2NRGe: R = 2,6-Me2C6H3, iPr, by silylene insertion into one of the Ge-N bonds to furnish the aminosilylgermylenes 8, R = 2,6-M e2C6H3, and 9, R = iPr. The X-ray structure analyses of these compound s revealed that 8 remains monomeric in the crystal with weak Ge Ge int eractions to the germanium atom of a neighbouring germylene molecule, whereas 9 dimerizes to give the strongly twisted (E)-1,2-diamino-1,2-d isilyldigermene (E)-10 with a long Ge-Ge double bond of 246 pm and a l arge trans-bent angle of 47.3 degrees.