NEW COMPOUNDS IN THE SYSTEM CAO SIO2/CACL2/H2O/

Authors
STADE H HEIDEMANN D WALLIS B
Citation
H. Stade et al., NEW COMPOUNDS IN THE SYSTEM CAO SIO2/CACL2/H2O/, Zeitschrift fur anorganische und allgemeine Chemie, 624(9), 1998, pp. 1551-1557
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
9
Year of publication
1998
Pages
1551 - 1557
Database
ISI
SICI code
0044-2313(1998)624:9<1551:NCITSC>2.0.ZU;2-S
Abstract
The hydrothermal formation of novel calcium silicate hydrates of compo sitions 5CaO . 2SiO(2). CaCl2. 4H(2)O, 5CaO . 2SiO(2). CaCl2. 2H(2)O a nd 4CaO . 2SiO(2). CaCl2. H2O from Ca3SiO5 and mixtures of CaO and SiO 2, respectively, in presence of calciumchloride at 200 degrees-350 deg rees C is described. From molybdate-reaction, Si-29 MASNMR, DTA and TG measurements it is concluded that these compounds are based on disili cate anions and are to be interpreted as calcium hydroxide disilicate chlorides.