Large quantities of volatile organic compounds (VOCs) are released by
terrestrial vegetation into the atmosphere. As a result of chemical re
actions of these biogenic VOCs the concentrations of several climatica
lly relevant trace species are significantly affected. There is substa
ntial evidence that biogenic hydrocarbons influence, for example, the
regional distribution of tropospheric ozone and the formation of organ
ic aerosols. The article attempts to elucidate the current state of kn
owledge about this particular part of the carbon cycle between biosphe
re and atmosphere. Furthermore, still open questions about the influen
ce of natural VOCs on chemical and physical processes in the troposphe
re are discussed.