CHARGE-COMPENSATED CARBARHODABORANES - SYNTHESIS AND MOLECULAR-STRUCTURES OF 3-L-3,3-(I)(2)-4-SME2-3,1,2-CLOSO-RHC2B9H10, L = CO OR PPH3

Authors
BOYD ASF ROSAIR GM TIARKS FBH WELLER AS ZAHN SK WELCH AJ
Citation
Asf. Boyd et al., CHARGE-COMPENSATED CARBARHODABORANES - SYNTHESIS AND MOLECULAR-STRUCTURES OF 3-L-3,3-(I)(2)-4-SME2-3,1,2-CLOSO-RHC2B9H10, L = CO OR PPH3, Polyhedron, 17(16), 1998, pp. 2627-2632
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
16
Year of publication
1998
Pages
2627 - 2632
Database
ISI
SICI code
0277-5387(1998)17:16<2627:CC-SAM>2.0.ZU;2-S
Abstract
Reaction of 3,3-(CO)(2)-4-SMe2-3,1,2-closo-RhC2B9H10 with iodine resul ts in the formation of 3-(CO)-3,3-(I)(2)-4-SMe2-3,1,2-closo-RhC2B9H10, 1. Reaction between 1 and PPh3 results in substitution of the carbony l group to afford 3-PPh3-3,3-(I)(2)-4-SMe2-3, 1, 2-closo-RhC2B9H10, 2. Both new compounds have been fully characterised by multinuclear NMR spectroscopy and also by a single crystal X-ray diffraction studies. ( C) 1998 Elsevier Science Ltd. All rights reserved.