LINE TENSION MEASUREMENTS THROUGH DROP SIZE DEPENDENCE OF CONTACT-ANGLE

Experiments with different organic liquids have been conducted to stud y the drop size dependence of the contact angles on a self-assembled m onolayer (SAM) surface of 1-octadecanethiol (HS(CH2)(17)CH3) on gold. Low-rate dynamic advancing contact angles were measured for sessile dr ops in vapor-saturated air using Axisymmetric Drop Shape Analysis-Prof ile (ADSA-P). The experiments were performed using a minimum of eight separately prepared SAM surfaces for each liquid. Although a degree of scatter in the measured contact angles existed, the general trend obs erved for each run was that the contact angles decreased as the radius of the three-phase line for the sessile drop increased from approxima tely 1 to 5 mm. To obtain a better view of the overall trend, the cont act angles from all of the individual runs for each liquid were averag ed at corresponding radii. Subsequently, the averaged results from the se experiments were interpreted using the modified Young equation. It was found that the drop size dependence of contact angles was due to a positive line tension. The line tension values are of the order of 1 mu J/m with a trend toward larger values for higher liquid surface ten sions. (C) 1998 Academic Press.