REVERSIBLE TRANSFORMATION BETWEEN METHYLENE AND METHYLIDYNE-HYDRIDE MOIETIES ON THE RU10C2 FRAMEWORK

Authors
LEE K WILSON SR SHAPLEY JR
Citation
K. Lee et al., REVERSIBLE TRANSFORMATION BETWEEN METHYLENE AND METHYLIDYNE-HYDRIDE MOIETIES ON THE RU10C2 FRAMEWORK, Organometallics, 17(18), 1998, pp. 4113-4116
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
18
Year of publication
1998
Pages
4113 - 4116
Database
ISI
SICI code
0276-7333(1998)17:18<4113:RTBMAM>2.0.ZU;2-L
Abstract
Oxidative substitution of [Ru10C2(CO)(22)(NBD)](2-) with ferrocenium i on and diazomethane forms a methylene compound, Ru10C2(CO)(22)(NBD)(mu -CH2), in which the methylene ligand symmetrically bridges two adjacen t apical ruthenium centers in the edge-fused bioctahedral Ru10C2 frame work. A methylidyne tautomer, Ru10C2(CO)(22)(NBD)(CH)(H), is formed re versibly at 80 degrees C.