Damascene Cu electroplating for on-chip metallization, which we concei
ved and developed in the early 1990s, has been central to IBM's Cu chi
p interconnection technology. We review here the challenges of filling
trenches and vias with Cu without creating a void or seam, and the di
scovery that electrodeposition can be engineered to give filling perfo
rmance significantly better than that achievable with conformal step c
overage. This attribute of superconformal deposition, which we call su
perfilling, and its relation to plating additives are discussed, and w
e present a numerical model that represents the shape-change behavior
of this system.