EXCEPTIONALLY BULKY LEWIS ACIDIC REAGENT, MAD

Authors
Citation
T. Ooi et K. Maruoka, EXCEPTIONALLY BULKY LEWIS ACIDIC REAGENT, MAD, Reviews on heteroatom chemistry, 18, 1998, pp. 61-85
Citations number
57
Categorie Soggetti
Chemistry
ISSN journal
09156151
Volume
18
Year of publication
1998
Pages
61 - 85
Database
ISI
SICI code
0915-6151(1998)18:<61:EBLARM>2.0.ZU;2-#
Abstract
The key feature of MAD is the exceptional steric hinderance created by the two bulky 2,6-di-tert-butyl-4-methylphenoxy ligands which prevent s it from self-association and hence makes it feasible to exsit as a m onomer in solution, thereby inducing the inherent oxgenophilicity of a luminum.