MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - MIXED AND MULTIPLE CLUSTER FUSION IN PLATINABORANE CHEMISTRY AND THE STRUCTURE OF [(PME2PH)(2)PTB16H17PTB10H11(PME2PH)] AS DETERMINED BY SYNCHROTRON X-RAY-DIFFRACTION ANALYSIS

Citation
J. Bould et al., MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - MIXED AND MULTIPLE CLUSTER FUSION IN PLATINABORANE CHEMISTRY AND THE STRUCTURE OF [(PME2PH)(2)PTB16H17PTB10H11(PME2PH)] AS DETERMINED BY SYNCHROTRON X-RAY-DIFFRACTION ANALYSIS, Journal of the Chemical Society. Dalton transactions, (17), 1998, pp. 2777-2778
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03009246
Issue
17
Year of publication
1998
Pages
2777 - 2778
Database
ISI
SICI code
0300-9246(1998):17<2777:MBCC-M>2.0.ZU;2-B
Abstract
Multiple cluster fusion between [(PMe2Ph)(2)PtB8H12] and molten B10H14 , gave the 26-boron species [(PMe2Ph)(2)PtB16-H17PtB10H11(PMe2Ph)] whi ch exhibits quite different structural and assembly features to the 26 -boron species [(PMe3)(2)IrB26H24Ir(CO)(PMe3)(2)] previously prepared from [(PMe3)(2)(CO)HIrB8H12] and B10H14.