PREPARATION OF CEDRANEDIOL BORONIC ESTERS

Citation
Yl. Song et al., PREPARATION OF CEDRANEDIOL BORONIC ESTERS, Synthetic communications, 28(20), 1998, pp. 3757-3764
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
28
Issue
20
Year of publication
1998
Pages
3757 - 3764
Database
ISI
SICI code
0039-7911(1998)28:20<3757:POCBE>2.0.ZU;2-N
Abstract
(-)-Cedranediol boronic esters 4, a series of asymmetric homologation reagents were prepared from a new chiral director (-)-cedranediol 3 an d boronic acids. (-)-Cedranediol 3 was easily synthesized by the dihyd roxylation of (-)-alpha-cedrene 2 with OsO4. A more convenient method for the preparation of boronic acids was developed as well.