NON SOLVENT REACTION - AMMONIUM ACETATE CATALYZED HIGHLY CONVENIENT PREPARATION OF TRANS-CINNAMIC ACIDS

Citation
Hms. Kumar et al., NON SOLVENT REACTION - AMMONIUM ACETATE CATALYZED HIGHLY CONVENIENT PREPARATION OF TRANS-CINNAMIC ACIDS, Synthetic communications, 28(20), 1998, pp. 3811-3815
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
28
Issue
20
Year of publication
1998
Pages
3811 - 3815
Database
ISI
SICI code
0039-7911(1998)28:20<3811:NSR-AA>2.0.ZU;2-Q
Abstract
trans-Cinnamic acids were obtained in near quantitative yield when var ious aromatic aldehydes were heated with equimolar quantity of malonic acid in presence of ammonium acetate under solvent free conditions. C onsiderable enhancement in the rate of the reaction was observed when the decarboxylative condensation was carried out under microwave irrad iation.