INFRARED AND RAMAN-SPECTRA OF DL-ASPARTIC ACID NITRATE MONOHYDRATE

Authors
RAJKUMAR BJM RAMAKRISHNAN V RAJARAM RK
Citation
Bjm. Rajkumar et al., INFRARED AND RAMAN-SPECTRA OF DL-ASPARTIC ACID NITRATE MONOHYDRATE, SPECT ACT A, 54(10), 1998, pp. 1527-1532
Citations number
27
Categorie Soggetti
Spectroscopy
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN journal
13861425 → ACNP
Volume
54
Issue
10
Year of publication
1998
Pages
1527 - 1532
Database
ISI
SICI code
1386-1425(1998)54:10<1527:IARODA>2.0.ZU;2-M
Abstract
Infrared and Raman spectral studies of DL-aspartic acid nitrate monohy drate help to determine the influence of extensive intermolecular hydr ogen bonding in the aspartic acid crystal. The presence of the carbony l rather than the carboxylic group indicates that the molecule is ioni c. The shifting of several group frequencies in the molecule confirms extensive hydrogen bonding. The anion fundamentals however continue to be degenerate. This indicates that its symmetry is unaffected in the molecule. (C) 1998 Elsevier Science Ireland Ltd. All rights reserved.