N. El et al., SOLVENT-FREE GLYCEROLYSIS CATALYZED BY ACETONE POWDER OF NIGELLA-SATIVA SEED LIPASE, Journal of the American Oil Chemists' Society, 75(9), 1998, pp. 1207-1211
The solvent-free glycerolysis of used sunflower oil catalyzed by aceto
ne powder of Nigella sativa seeds was investigated. The highest partia
l acylglycerols yield was obtained at 60 degrees C. The glycerolysis r
eactions, conducted at molar ratios of 1:1, 2:1, and 3:1 of oil to gly
cerol keeping the acetone powder content at 30% based on oil weight an
d the temperature at 60 degrees C, approached equilibrium after 2 h. T
he highest partial acylglycerol content of the products was 66% (1:1 m
olar ratio) and 60% (2:1 molar ratio).