NEW APPROACH TO THE THEORY OF CIRCULAR-DICHROISM

Citation
J. Zamastil et al., NEW APPROACH TO THE THEORY OF CIRCULAR-DICHROISM, Collection of Czechoslovak Chemical Communications, 63(8), 1998, pp. 1187-1201
Citations number
9
Categorie Soggetti
Chemistry
ISSN journal
00100765
Volume
63
Issue
8
Year of publication
1998
Pages
1187 - 1201
Database
ISI
SICI code
0010-0765(1998)63:8<1187:NATTTO>2.0.ZU;2-Y
Abstract
Using the semiclassical approach for the description of the propagatio n of the electromagnetic waves in optically active isotropic media we derive a new formula for the circular dichroism parameter. The theory is based on the idea of the time damped electromagnetic wave interacti ng with the molecules of the sample. In this theory, the Lambert-Beer law need not be taken as an empirical law, however, it follows natural ly from the requirement that the electromagnetic wave obeys the Maxwel l equations.