V. Vassileva et al., PHOTOCHEMICAL BEHAVIOR OF NATURAL SILK - III - PHOTOFADING OF SILK DYED WITH ACID AZO DYES, Polymer degradation and stability, 61(3), 1998, pp. 367-373
The photochemical behaviour of orange, red and blue mono azo dyes, whi
ch were distributed into fibroin macromolecules has been investigated
in this study. Some of the samples were treated with a UV-absorber. Th
e extent of photofading was evaluated by means of the colour differenc
e Delta E. A linear correlation between Delta E and the content of car
bonyl groups with high coefficient of correlation (R=0.99) was obtaine
d. New experimental evidence for the photoreduction mechanism of azo d
yes in silk fibers was established. (C) 1998 Elsevier Science Limited.
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