STEREOSELECTIVE SYNTHESIS OF GAMMA-AMINOALLYLTINS FROM VINYLTIN ACETALS

Authors
SUZENET F BLART E DESTOUCHES M QUINTARD JP
Citation
F. Suzenet et al., STEREOSELECTIVE SYNTHESIS OF GAMMA-AMINOALLYLTINS FROM VINYLTIN ACETALS, Journal of organometallic chemistry, 567(1-2), 1998, pp. 21-23
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
567
Issue
1-2
Year of publication
1998
Pages
21 - 23
Database
ISI
SICI code
0022-328X(1998)567:1-2<21:SSOGFV>2.0.ZU;2-J
Abstract
gamma-Aminoallyltins were obtained by reacting RCuCNMgCl/BF3. Et2O wit h aminoacetals derived from beta-tributylstannylacrolein. The control of the stereochemistry of the double bond and of the absolute configur ation of the newly created allylic carbon centre was proved possible. (C) 1998 Elsevier Science S.A. All rights reserved.