ORGANOSAMARIUMS - PREPARATION USING DIIODOSAMARIUM AND REACTIVITY IN TETRAHYDROPYRAN

Authors
HAMANNGAUDINET B NAMY JL KAGAN HB
Citation
B. Hamanngaudinet et al., ORGANOSAMARIUMS - PREPARATION USING DIIODOSAMARIUM AND REACTIVITY IN TETRAHYDROPYRAN, Journal of organometallic chemistry, 567(1-2), 1998, pp. 39-47
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
567
Issue
1-2
Year of publication
1998
Pages
39 - 47
Database
ISI
SICI code
0022-328X(1998)567:1-2<39:O-PUDA>2.0.ZU;2-A
Abstract
Diiodosamarium prepared in tetrahydropyran reduces allylic, benzylic a nd alkyl halides at 0 or -15 degrees C to give organosamariums which a re stable under these conditions. The reactivity of these organometall ics has been explored, showing that they are very selective reagents. (C) 1998 Elsevier Science S.A. All rights reserved.