NEW SYNTHESIS OF THE NANOBUILDING BLOCK USN)(12)O-14(OH)(6))(2-14(OH)(6))(O3SC6H4CH3)(2)() AND EXCHANGE PROPERTIES OF ((BUSN)(12)O)

Authors
EYCHENNEBARON C RIBOT F SANCHEZ C
Citation
C. Eychennebaron et al., NEW SYNTHESIS OF THE NANOBUILDING BLOCK USN)(12)O-14(OH)(6))(2-14(OH)(6))(O3SC6H4CH3)(2)() AND EXCHANGE PROPERTIES OF ((BUSN)(12)O), Journal of organometallic chemistry, 567(1-2), 1998, pp. 137-142
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
567
Issue
1-2
Year of publication
1998
Pages
137 - 142
Database
ISI
SICI code
0022-328X(1998)567:1-2<137:NSOTNB>2.0.ZU;2-J
Abstract
This paper deals with a new and easy way to synthesize the macrocation {(BuSn)(12)O-14(OH)(6)}(2+) from BuSnO(OH) and p-toluene sulfonic aci d. It was isolated by crystallization as {(BuSn)(12)O-14(OH)(6)}(O3SC6 H4CH3)(2)C4H8O2. Exchange properties of sulfonates with different anio ns have been studied in several solvents by using Sn-119- and H-1-NMR. Sulfonate anions can be exchange in isopropanol by acetate or hydroxy l groups by reaction with sodium acetate or tetramethylammonium hydrox ide, respectively. (C) 1998 Elsevier Science S.A. All rights reserved.