M. Bylicki et Ca. Nicolaides, THE H-2-S-4(0) SPECTRUM HAS AT LEAST 2 RESONANCE STATES, Journal of physics. B, Atomic molecular and optical physics, 31(17), 1998, pp. 685-690
A revival of interest in the prototypical doubly negative ion H2-, has
led to a current disagreement as to whether there exists a S-4(o) res
onance above the H 2p threshold. Our herein reported complex coordinat
e rotation calculations show that the H2- spectrum has at least two co
mplex eigenvalues, z, corresponding to quasilocalized S-4(o) states. T
he first is 1.43 eV above the n = 2 H threshold, with -2 Im(z) = 1.69
eV. The second is 0.46 eV above the n = 3 threshold, with -2 Im(z) = 0
.29 eV. The large value of -2 Im(z) for the lowest S-4(o) state sugges
ts that the a priori qualitative identification of -2 Im (z) with a ra
te of decay (width) should be considered as a reasonably good but not
rigorous relation, whose understanding should await precise measuremen
t of the spectral density of this state.