SYNTHESIS AND CHARACTERIZATION OF A 5-COORDINATE 1 1 ADDUCT DERIVED FROM DIPHENYLTIN(IV) DICHLORIDE AND 6-METHOXY-2-[(4-CYANOPHENYLIMINO)METHYL]PHENOL/

Authors
YEAP GY ISHIZAWA N NAKAMURA Y
Citation
Gy. Yeap et al., SYNTHESIS AND CHARACTERIZATION OF A 5-COORDINATE 1 1 ADDUCT DERIVED FROM DIPHENYLTIN(IV) DICHLORIDE AND 6-METHOXY-2-[(4-CYANOPHENYLIMINO)METHYL]PHENOL/, Journal of coordination chemistry (Print), 44(3-4), 1998, pp. 325-333
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry (Print) → ACNP
ISSN journal
00958972
Volume
44
Issue
3-4
Year of publication
1998
Pages
325 - 333
Database
ISI
SICI code
0095-8972(1998)44:3-4<325:SACOA5>2.0.ZU;2-J
Abstract
Reaction of diphenyltin(IV) dichloride with 6-methoxy-2-[(4-cyanopheny limino)methyl]phenol results in the formation of an adduct with 1:1 (o rganotin: ligand) stoichiometry and coordination of the ligand to the Sn atom occurs via the phenolic oxygen atom. An X-ray crystal structur al study of thoxy-2-[(4-cyanophenylimino)methyl]phenol]tin(IV) has bee n carried out using a charge-coupled device (CCD) area detector diffra ctometer. The Schiff base and the resulting adduct were characterized by elemental analysis, H-1, C-13 and Sn-119 NMR spectroscopies.