A CONVENIENT PREPARATION OF TAXOID RIGHT-HALF BUILDING-BLOCKS

Authors
ARSENIYADIS S DELMORAL JQ ALVES RB POTIER P TOUPET L
Citation
S. Arseniyadis et al., A CONVENIENT PREPARATION OF TAXOID RIGHT-HALF BUILDING-BLOCKS, Tetrahedron : asymmetry, 9(16), 1998, pp. 2871-2878
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
16
Year of publication
1998
Pages
2871 - 2878
Database
ISI
SICI code
0957-4166(1998)9:16<2871:ACPOTR>2.0.ZU;2-9
Abstract
Wieland-Miescher ketone derived unsaturated diols 4 reacted with Pb(OA c)(4) to furnish tricyclic enolether intermediate 6 which upon ozonoly sis gave access to useful synthetic intermediates such as bicyclic lac tone 7, methyl furanoside 8 and triol 9 (taxoid right-half precursors) , depending on the solvent used during the ozonolysis and the nature o f the following synthetic operation. (C) 1998 Elsevier Science Ltd. Al l rights reserved.